PokéBase - Pokémon Q&A
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Because when you find a gym leader out of their gym, they usually register their number in your Pokegear so that you can call them for a rematch.

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See here: http://pokemondb.net/heartgold-soulsilver/gym-rematch

Summary:

  • Falkner: Monday all day, Celadon Dept. Store
  • Bugsy: Thursday all day, Viridian Forest (south)
  • Whitney: Every day 12:00-16:00, Goldenrod Dept. Store
  • Morty: Mon/Tue all day, Outside Bell Tower
  • Chuck: Every day, talk to wife outside Cianwood gym
  • Jasmine: Every day 13:00-14:00, Olivine Dining Room
  • Pryce: Every day 06:00-10:00, Lake of Rage (west)
  • Clair: Every day 06:00-10:00, Dragon's Den
  • Brock: Every day 12:00-15:00, Diglett's Cave
  • Misty: Every day 16:00-18:00, Cerulean Cape (Route 25)
  • Lt. Surge: Every day 09:00-12:00, Ouside Power Plant (show him Pikachu)
  • Erika: Sat/Sun 15:00-17:00, Celadon City fountain
  • Janine: Every day 16:00-18:00, Reception Gate (Victory Road)
  • Sabrina: Friday all day, Olivine City harbour
  • Blaine: Tuesday all day, Cinnabar Island
  • Blue: Every day 15:00-16:00, Pallet Town (talk to Daisy)
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thanks :)
I'll give you this one ShinyFlygon xD