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I have a egg move skarmory and i want to give him perfection with those medicines and not mess anything up.

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What game?

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Any LV it doesnt make a differnce.
I would prefer to use them early just in case you battle other wild pokemon that give off evs.
That is why its a good idea to ev train as early as possible.
But try not to waste your money, the evs will show graduly.

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