Answer 1

http://pokemondb.net/tools/moveset-search

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Did you forget that this site had this tool??

I checked for Pokemon that can learn both, and the only one that popped up is Corsola. Smeargle is, as J98 said, common knowledge.

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Corsola can learn both moves at the same time as well.

• Aqua Ring: Learns this move at Level 37.

• Ingrain: Learns this move by breeding.

  • Father: Lileep or Cradily that knows Ingrain
  • Mother: Corsola

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\m/o_o\m/

Comments

can they be used same time?

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check my edited answer.

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UberPwnage, he comment saying can they both be USED at the same time.

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oo. Well, yes they can be used at the same time. I have read nothing to suggest otherwise.

Answer 2

Yes and yes. The Pokemon who can learn them both is Smeargle.

Source: Experience and common knowledge.