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If a Pokemon has 0 defense/ SP.Defense, will it always be 1HKO'd?

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If they have Sturdy or a Focus Sash then no. Otherwise it depends on the attack of the opponent. For example if a Chimchar with 1 Atk and used Scratch on a Pokemon with 0 Def then it wouldnt do that much damage. But if a Infernape with 300+ Atk used Close Combat on a pokemon with 0 Def then yes OHKO.

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