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When did Ash's Palpitoad learn Sludge Wave ?

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In episode 9 of Adventures in Unova, Ash is battling Stephan and Palpitoad uses Sludge Wave wich makes Zebstrika Poisoned.When did it learn that move ?

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It learns it in Strong Strategy Steals the Show!. BW106.

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so it has not used it before....