PokéBase - Pokémon Q&A
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I want to know this because it's nice to be able to switch out at the end of a turn and start the next one with a fresh Pokémon ready to go. The slowest one I found so far was Mega Ampharos (with a base Speed stat of 45). If anyone can help me, that would be great (and by the way I'm looking for only FE Pokémon).

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Sentret and Vespiquen are the slowest users of U-Turn. whilst Klink and Probopass are the slowest users of Volt Switch (Probopass isthe slowest fully evolved Pokemon).
Source:
https://www.smogon.com/bw/moves/volt_switch
https://www.smogon.com/bw/moves/u-turn

You can use these to easily find the slowest users of these moves that best fits your team.

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