Answer 1

Porygon 2, Porygon-Z, Serperior, Emboar, Samurott, Stoutland, Purrloin, Liepard, Simisage, Simipour, Unfezant, Boldore, Gigalith, Gurdurr, Conkeldurr, Seismitoad, Throh, Sawk, Whimsicott, Petilil, Lilligant, Krookodile, Maractus, Crustle, Sigilyph, Tirtouga, Carracosta, Garbodor, Cinccino, Gothorita, Duosion, Reuniclus, Vanillish, Vanilluxe, Karrablast, Amoonguss, Jellicent, Ferroseed, Ferrothorn, Klink, Klang, Klinklang, Eelektrik, Cryogonal, Shelmet, Accelgor, Mienfoo, Mienshao, Pawniard, Bisharp, Rufflet, Braviary, Vullaby, Mandibuzz, Heatmor, Durant, Deino, Zweilous, Hydreigon, Larvesta, Volcarona, Cobalion, Terrakion, Virizion, Tornadus, Thundurus, Reshiram, Landorus, Kyurem, Keldeo, Meloetta, and Genesect, all have never been seen in the anime yet.

Comments

actually, in the most RECENT episode, Ash FINALLY defeated Trip's Serperior, thanks to an Electro-Ball-Iron-Tail combo. Man, it was sweet. the look on Trip's FACE sent me laughing. He was in total shock. I don't think Trip expected to be defeated by an ELECTRIC type. What amazes me is that Trip and Ash actually shook hands in the Pokemon Center. I was like "WHAT THE...?". I was, and still am, confused by that little hand-shake.

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wait, maractus?? i thought cilan had one

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@ cheren2345: What does that have to do with the answer?
@ Lynx 33: That answer was posted before he received a Maractus, possibly?

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There was an episode were the character of the day had three maractus. The only ones yet to appear I believe are genescect, who'll soon get a movie, and the x and y pokemon if I'm correct.
Cilan, as far as bulbapedia knows, has no maractus in the anime ( only in the game)

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LIEPARD IS IN THE ANIMIE!!!