PokéBase - Pokémon Q&A
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To get Eevee, you have to go inside the Castelia Sewers, until you find another exit to the Castelia City park.

In the Castelia City park grass, there is a 5% or 1/20 chance that you will find Eevee.

Good Luck. :)

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My source tells where to find it...
Hehe I got eevee the first time I stepped into the grass when I was doing the Nuzlocke Challenge. I got lucky! :)
There is another way to get an Eevee, after defeating the elite four, you have to talk to Fennel and she gives you a free Eevee with its hidden ability.
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B/W 1: you cannot get it....

B/W 2: it is rare...

Source: http://pokemondb.net/location/unova-castelia-city#gen5

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I got one in Black and White 1...
Did you get it through trade? It shouldn't be possible unless if you traded...
I spin traded with my friend who has black 2
Well, I meant you cannot get it as in you can't get it without trade...