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In castelia city, in the north fountain, there is a dancer. Talk to him, then find his buddies, one at one of the piers the other in the narrow road, and then they will give you amulet coin.

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You get it in castelia city after you unite the three dancers(Edmond, Mickey, and Raymond) at the water fountain.
Source: http://bulbapedia.bulbagarden.net/wiki/Amulet_Coin#Amulet_Coin

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