PokéBase - Pokémon Q&A
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I haven't found any sources that say it doesn't..but I haven't found any sources saying it does? so maybe some can help me out! Thanks bros

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Leftovers is only found at S.S Tidal, located in the bottom-deck storage in the top left area near some crates. The only other way to get leftovers before post-game is through pickup.

If you want to get Leftovers before the post-game then your only option is to use the Pickup ability. Any Pokémon at Level 81 or higher with the Pickup ability has a 1% chance of picking up Leftovers after every battle — even if the Pickup Pokémon didn't participate in the fight.

Source: this

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No, the only one is on on S.S Tidal on the bottom floor, I believe

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