PokéBase - Pokémon Q&A
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I have gave it a soothe ball and walked around with it and it has 255 happiness (Unless its not the max) and its not evolving yet. What do I do?

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In order to get a Lucario, you must level up a Riolu with high friendship during the day time. If it's not day time, between 10:00 AM and 7:59 PM, your Riolu won't evolve.

Source: knowledge

I hope I helped!

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Make sure its during daytime as that is when it can only evolve

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