Spikey Shield, Water Shruiken and Mystical Fire?

Question

If Mismagius can now use Mystical Fire and Spikey Shield Cacturne, then does any other Pokemon use Water Shuriken?

Answer 1

The Pokemon Accelgor can learn Water Shuriken at level one (go to the move relearner)

Source: http://bulbapedia.bulbagarden.net/wiki/Water_Shuriken_(move)