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Does it just restore 20 hp?

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It does restore 20 hp, but if you take it and use one on the statues outside of relic castle. Which is found in the desert resort. ( If you Didn't know )

You can get a Zen Mode Darmanitan.

http://pokemon.marriland.com/black_white/walkthrough/postgame/relic_castle

http://pokemondb.net/pokedex/darmanitan

http://pokemondb.net/ability/zen-mode

These Zen Mode Darmanitans turn into zen mode after they reach half health, but beware when trying to catch him, that he knows Flare Blitz and you are in a sandstorm, so its very easy for him to kill him self. ( Or Faint )

Hope This Helps :D

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You can also get a rage candy bar at the royal unova and icirrus town (winter)
Nuthin to add