PokéBase - Pokémon Q&A
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You can teach your Serperior Frenzy Plant after the pokemon league. The tutor is on Route 13.

Thanks, Darth. You also need to have maxed happiness.

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You need to have maxed happiness, however
same thing I had a Serperior and I taught it frenzy plant, Its a great move.
and your answers pretty good too.