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The guy in black that gives you free items daily that stands next to the tutor house.

Located in Route 13

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Best answer

from serebii

Yellow Flute

Red Flute

Black Flute

White Flute
   Blue Flute	        
Shoal Salt	 

Shoal Shell

Lucky Egg	        
DeepSeaTooth
DeepSeaScale	
Dragon Scale	
Razor Fang	
Razor Claw	
Reaper Cloth	
Dubious Disc	
Magmarizer
Electirizer	        
Protector	        
Up-Grade	        
Lucky Punch	
Metal Powder	
Thick Club	       
Stick	                
King's Rock	
Metal Coat	        
Heart Scale	
Big Pearl	    		
Heart Scale	
Rare Candy	
Max Revive	
Stardust	        
Pearl	                
Stardust
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