PokéBase - Pokémon Q&A
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Nope...
It is impossible to catch without an event.
You can still trade for one.

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Actually, there is no other way to catch it without an event. Unless, you get it from a trade or from an Action Replay (AR). (Hope This Helps!)

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When B&W first came out you could get a free celebi at gamestop, but only at events or trade now.

Or action replay/poke-nav

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