Meta Rate My Team PokéBase - Pokémon Q&A
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Psychic: Yes.
Psyshock: Yes.
They both can be found near Giant Chasm, which is accesible before the Elite Four. Psychic is on Route 13, which is close.

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Giant Chasm is accessible before the elite four! :DDDDDDDDDDDDDDDD
Yep. You have to battle Kyurem-B / W there.