Every time a Grotto regenerates, there is a 40% chance for a hidden item to spawn and a 40% chance for a visible item to spawn.
Items in all Grottoes
Visible items (all Grottoes)
Poke Ball: 12.5%
Great Ball: 5%
Ultra Ball: 2%
Potion: 6.25%
Super Potion: 2.5%
Hyper Potion: 1%
Repel: 6.25%
Super Repel: 2.5%
Max Repel: 1%
Hidden items (all Grottoes)
Damp Mulch: 6.25%
Growth Mulch: 6.25%
Stable Mulch: 6.25%
Gooey Mulch: 6.25%
TinyMushroom: 7.5%
Big Mushroom: 2.5%
Red Shard: 1%
Green Shard: 1%
Yellow Shard: 1%
Blue Shard: 1%
Rare Candy: 0.25%
PP Up: 0.5%
PP Max: 0.25%
Items in specific Grottoes
Routes 2, 3 (one), 5, 6 (one), 7, 9, 13, 18, 22, 23; Floccesy Ranch; Giant Chasm; Abundant Shrine (one); Lostlorn Forest; Pinwheel Forest (both)
Fire Stone: 0.25%
Water Stone: 0.25%
Thunderstone: 0.25%
Leaf Stone: 0.25%
Routes 6 (one), 13; Abundant Shrine (one)
Moon Stone: 0.25%
Sun Stone: 0.25%
Shiny Stone: 0.25%
Dusk Stone: 0.25%
Route 3 (one)
Dawn Stone: 1%
Hidden Grotto (Bulbapedia)