PokéBase - Pokémon Q&A
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This question has been bugging me for a while.

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To unlock all the Master Tournaments.You first need to beat the Mix and Rental Tournament.Which is after you defeat the Drifveil Tournament.Then you need to beat the Elite Four to access the Unova Leaders Tournament.After you beat the Unova Leaders Tournament,you have to beat the Kanto,Johto,Hoenn,and Sinnoh Leaders Tournament to access the Mix and Rental Master Tournament.In the process of beating the Mix and Rental Tournament,you also unlock the Type Expert Tournament after you beat the Kanto,Johto,Hoenn,and Sinnoh Leaders Tournament,and you will also unlock the World Leaders Tournament.

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Do you mean the Mix Masters Tournament?

If so, the requirement is to defeat Mix Tournament and World Leaders.

Mix Tournament will be unlocked after the first time you beat the Driftveil Tournament.

Serebii source