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And, can I catch them if I have played white 2, but not white or black 1.

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Purrloin
Timburr
Tympole
Woobat
Sandile
Darumaka
Darmanitan
Scraggy
Sigiliph
Zorua
Boldore
Ferroseed
Klink
Joltik
Source: http://bulbapedia.bulbagarden.net/wiki/N's_Pokemon

And yes, you can catch them without having played Black or White 1, however, I do recommend that you play one of those first, since the storyline in Black and White2 is largely based off of Black and White 1.

Note: You must have used the Memory Link to encounter N's Pokemon, except for Zorua, which is a gift.

'If you have two DS Handhelds, you can establish a link using both at the same time.

Insert Pokemon Black 2 or White 2 in one DS. Select the Memory Link option from the Unova Link Menu at the start menu. THE GAMES DO NOT HAVE TO BE THE SAME COLOR. You can use White's memories with Black 2, and Black's memories with White 2.

On the other DS, select "Download Play" from the DS Menu before starting up the game. Select the Pokemon option in the Download Play, and wait for the game to establish a link. A message will pop up on the first DS confirming the link.
Wi-Fi

If you don't have two DS Handhelds, you can establish a link over Wi-Fi. Remember, you need WEP Encryption or no Encryption when using Nintendo Wi Fi. That being said, DSi and 3DS users can set up "advanced" connections for WPA2 Encryption.

Register the first Pokemon Black or White at the Pokemon Global Link. To do so, you'll need to use the Game Sync feature at the Main Menu of the first Pokemon Black or White. Use the Game Sync ID to register the game at Pokemon Global Link after creating an account.

Next, insert Pokemon Black 2 or White 2 into the DS. Start up the game and select the Memory Link option from the Unova Link menu at the start menu. Select the Wi-Fi option and enter the same Game Sync ID. A message will pop up confirming the link. '-IGN
Source: http://www.ign.com/wikis/pokemon-black-white-version-2/Memory_Link

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Hmm..link isn't working..
How do you use the memory link?
I also forgot to ask this: Do they have their hidden abilities?
OK, I edited how to use memory link. I'm fairly certain that you can use a friend's game instead of your own Black/White1.
As for the Abilities, no, they don't, but Purrloin has Limber and Tinburr has Guts, despite their Abilities being different in Black and White1.
Please note that the IGN Source will try to open up pop-up windows and stuff, I'm not garunteeing the safety of the link.
Great answer! Thanks.
NP, happy to help. :)