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What is the best Pokemon to use my master ball on?

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I am planning to use a Metang on my team but I am wondering if I should use my master ball on it as it is hard to catch.

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I would actually not use it on a simple Metang...
You really should save your Master Ball for hard to catch Legendary Pokemon. Such as:

  • Regigigas
  • Cresselia
  • Heatran
  • Kyurem
  • [email protected]

One of those work well.

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