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Hello. I've killed my Volcarona on Black2, cause I was following a walkthru that said that I could beat it and then catch it after beating the Elite 4. The thing is, I've beaten the E4, and Volcarona isn't there. What should I do?

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Perhaps you've been to the wrong room? You can go and beat the Elite 4 one more time and try again.

Relic Castle, Marriland guide

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Nop, the right room, for sure. But it's right, Volcarona reappears then? I didn't wanted to beat E4 again without being sure of it.
Usually, re-defeating the E4 will work. I did that for Kyurem, so it should be the same for Volcarona.