PokéBase - Pokémon Q&A
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To get Larvesta, you must breed Volcarona who is found in the Relic Castle, accessible by the PTW iirc.

Source: Experience

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yeah thats what im going to do
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You have to breed the Volcarona you get from the Relic Castle because it is unobtainable in B/W 2.

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The only way to obtain Larvesta in BW2 is by hatching it from a Volcarona. Volcaron can be caught in Relic Castle

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