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I got the Event Deoxys at Lv.100 (of course). So, if my Deoxys Battles 252 Bidoofs, will it get 252 HP EVs (also with any other Pokemon and stat)?

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In Gen 5, you can EV train level 100 pokeomn because the EVs are applied as earned, not by level up. So you'll need to obtain some of the berries that erase EVs, and get rid of all the EVs your Deoxys currently has. If you have an AR, it is easy to get said berries. Clear all of it's EVs, and then you can re-EV train it in the stats you want. Note that you can't find Bidoof in Black and White 2, I suggest doing it in the swamps of Icirrus City, where Stunfisk and Palpitoad can give you HP EVs.

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gdi Ben. That's the second time /.\
You think I never posted any wrong answers? It happens. And btw you didn't have to hide, I'd be okay with you editing it.
nah, you have a good answer. Don't need two answers on a page with a good answer already :P
Oh, should I use PokéCalc to figure out my EVs? Also, which berries reduce which stat?
Also, I was just using Bidoof as a metaphor.
They're listed on this link

http://pokemondb.net/ev