PokéBase - Pokémon Q&A
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The icy rock is the method for evolving Eevee into Glaceon. You bring an Eevee, level it up around the icy rock, and it will evolve.
Source: Experience.

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It evolves Eevee into Glaceon when you level it up near the rock.

Source: Experience

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Eevee, when leveled up in the presence of the Icy Rock, evolves into Glaceon. That's the only purpose the rock serves.

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My source is also experience