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I got it to of using rain dance and it didn't evolve

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You have to evolve it on a Route that is raining at level 50+. For example It rains quite a bit on route 14. Just Give it a rare candy or level up there once its raining.

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At level 50 when it is raining.
Source: Sliggoo pokedex in database
http://pokemondb.net/pokedex/sliggoo

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