PokéBase - Pokémon Q&A
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I'm just asking these questions. :P

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The upgrade of the Mega Ring helps you detect underground Mega Stones, similar to how a dowsing machine detects underground/hidden items. However, the upgrade only works when sun hits the Anistar Sun Dial, or between the hours of 8-9 PM, on your 3DS time.

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The upgraded Mega Ring allows you to hunt for the Mega Stones across the region within 8-9 hours in the evenings. If you need to upgrade the mega ring, go to Kiloude city, do a round of the battle mansion, then fight your rival (at the north part of Kiloud city), then she will tell you where to go.

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