PokéBase - Pokémon Q&A
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When a Pokémon with Volt Absorb is hit by an Electric-type move, its HP is restored by one quarter of its maximum HP, and the move will have no effect.

It will always be 25% because volt absorb always heals 25% of health of a Pokemon when hit by an electric move. Although there is an exception to this because in 3rd gen, thunder wave is unaffected by volt absorb and will restore 0 health to the Pokemon and also paralyze.

Source: http://bulbapedia.bulbagarden.net/wiki/Volt_Absorb

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