PokéBase - Pokémon Q&A
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in this site it says it can find leftover so can it in X and Y?
also can it find TMs in gen 5/6 as TMs are infinite?

"Items picked up range from Potions, Great Balls, Ultra Balls and Rare Candies up to Leftovers and some TMs. Better items have a lower chance of being found; furthermore, higher-level Pokémon will obtain better items." -pickup DB

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Yes a Pokémon that has the Pickup Ability can pickup Leftovers in Pokémon X and Y.

You have a 1% chance of the Pokémon with the Pickup Ability, picking up Leftovers in Pokémon X and Y if that Pokémon is between Level 81 and 90 or 91 and 100, and of course it is in your party.

Source: http://bulbapedia.bulbagarden.net/wiki/Pickup_(Ability)#Pok.C3.A9mon_X_and_Y

Hope I helped :)

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thanks
No problem, glad I could help :)
now just to train a pickup pokemon up to level 81-100 yey
You still have a 1% chance so it isn't that simple
i´ve been walking for like 30 minutes it hasnt picked up anything (its a poketransfered lillipup lvl100)
you don't walk around…you pick up items from battles