PokéBase - Pokémon Q&A
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What are the chances for each hit, like 2 is so-and-so percent, and so on.

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For moves that hit 2-5 times in a row, the chances are now

  • 1/3 for 2 times
  • 1/3 for 3 times
  • 1/6 for 4 times
  • 1/6 for 5 times

Prior to Gen 5 they were

  • 3/8 for 2 times
  • 3/8 for 3 times
  • 1/8 for 4 times
  • 1/8 for 5 times

However, if the Pokemon has the ability Skill Link, these moves will always hit five times in a row

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2 Hits 33.3%
3 Hits 33.3%
4 Hits 16.7%
5 Hits 16.7%
(Gen 5 Onwards)

>Most multi-strike moves will hit an opponent two, three, four, or five times in one turn. These moves are more likely to hit two or three times, but will always hit five times when used by a Pokémon with Skill Link.

Note: Check here for more info and to see different percentages for Gen 4 lower

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From Gen I-IV:

  • 2 hits 37.5%
  • 3 hits 37.5%
  • 4 hits 12.5%
  • 5 hits 12.5%

Gen V onwards:

  • 2 hits 33.3%
  • 3 hits 33.3%
  • 4 hits 16.7%
  • 5 hits 16.7%

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Source

Hope I helped.

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