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I was thinking of ev training a Pokemon With 180 in a certain stat and usually I get 50 ev points per horde so if I do 3 hordes to get 150 then add 30 for vitamins should I put the 30 on first from the vitamins before I ev train or after I ev train?

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Do the vitamins first! After you go pass 100 ev's vitamins will no longer work! For example, If you have 90 evs you can still use a vitamin, but if you go over 100 you no longer can use them! Also on a side note, if you have 98 evs it will only give you 2 evs. Hope this helped!

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