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I'm keeping my Dragonair at its stage - not evolving it - but I breed one and got all 6 IVs, and hidden ability, but it has a serious nature - is that good?
What's the best nature for Dragonair with the hidden ability also?

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The best nature for Dragonair/Dragonite is Adamant since it boosts your attack . But serious doesn't lower anything or raise anything so that might be ok but overall the besy physical dragonite always have Adamant Nature,

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so should i stick with Serious Nature? or try and get a Adamant Nature?
Try and breed it still with multiscale and 6 IVs to get Adamant.If you don't want to Serious is fine :P
well i just went ahead and kept it serious nature cause i couldn't get a good Adamant nature, its surprisingly doing really good but with the serious nature what should i train it in?
nature -Adamant
Dragon Dance
Dragon Claw
Extreme speed

item- weakness policy
You should train it in HP and attack if you want a physical one :P