PokéBase - Pokémon Q&A
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Best as in power, accuracy, and moves actually worth while.

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Everything that's not Psyshock and Stone Edge.
Ok thanks

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Volt Switch
Hyper Beam- has to Recharge
Giga Impact- has to Recharge
Thunder- Bad accuracy
Thunderbolt
Fire Blast - bad Accuracy
Flamethrower
Swords Dance
U-turn
Wild Charge
Brick Break
Shadow Ball
Ice Beam
Earth Quake
Dragon Claw
Toxic - 90 accuracy

Please tell me if you need waterfall for these.
I will add more, just need to check....
Hope this Helped

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You can't get Volt Switch until Kiloude City.
But you don't need Waterfall