Meta Battle Subway PokeBase - Pokemon Q&A
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It really depends on the needs of your team, Carbink's defense and special defense are both base 150. If your team is in need of a physically defensive Pokemon than bold is the nature you should go for, if your team needs more special bulk than calm is the better nature. To prevent being taunt bait moonblast should be added for stab.

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It honestly depends on whether or not you're planning to use your Carbink as a special wall or not.

Smogon recommends a Bold nature, due to the physical threats in NU.

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