PokéBase - Pokémon Q&A
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I've been hiatus from Pokemon and now I'm back and is wondering if my perfect iv Charizard and others with the same can take on online battles like ou tiers

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There's no Smogon tiers for WiFi battles.

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Near perfect IVs are required in competitive. Perfect is expected. Charizard is suitable and allowed in OU. As for any other questions about tiers, you can just search Smogon.

I don't know if you're new to Gen 6 competitive, but if so then you've got a lot to catch up on before Gen 6 OU competitive if you haven't done Gen 6 competitive before. A lot has changed since Gen 5. There are a lot of good Megas in OU, and with them comes new battle dynamics and expectations.

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Thanks I appreciate it