PokéBase - Pokémon Q&A
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Question is pretty self-explanatory. Ty for awnsering!

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The ability Pick-Up only works when you go into battle and leave the battle. Once you leave the battle, you have a 10% chance of the Pokemon with said ability having an item.
The Pick-Up ability does not have anything to do with how many Pokemon are in battle.

Sorry it doesn't, though...
That would be awesome.

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