Meta Rate My Team PokéBase - Pokémon Q&A
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Title says all.

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No, Eviolite only works on Pokémon that can evolve.

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The Eviolite will only work on Pokemon that can evolve such as Pikachu, because it can evolve into Raichu, but Raichu can't use it because it cannot evolve. Pokemon with no evolutionary line cannot use it at all.

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