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EV training starts with Vitamins. What are all the places I can buy Vitamins in B2/W2?

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You can buy Vitamins in Shopping Mall Nine, 3rd floor, left cashier on Route 9.

Source- https://bulbapedia.bulbagarden.net/wiki/Shopping_Mall_Nine

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Ty :) How about with BPs? Or was it possible in B2/W2? I use my BPs for TMs and Items but BP shopping locations could also be added to the answer ;)
yes. You can exchange vitamins for BPs at the Battle Subway, and PWT (Pokemon World Tournament) for 1 BP https://bulbapedia.bulbagarden.net/wiki/Pok%C3%A9mon_World_Tournament#Items and https://bulbapedia.bulbagarden.net/wiki/Battle_Subway