PokéBase - Pokémon Q&A
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What do you want to do with this Gyarados? Are you using it to battle in-game trainers, other people, or something else? Sometimes Gyarados's special defense doesn't matter, and you're better off investing in physical attack and speed.

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Here are some items you can use to raise Spec. Def.:

Zinc (using them outside of battle will raise the stat)
X Spec. Def. (used in battle and will only last for the until the end of battle/ when the Pokemon is swapped)
Power Band (Raises Spec. Def. EV's after gaining experience)

Defeating wild Drowzee's will grant Spec. Def. EV's when defeated. (found on route 2 in US/UM)

Hope I help!

Source: this and this, and finally this

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Deep sea scales only work on Clamperl.
I'll remove that.