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My Darmanitan is lv42, but still hasn't learned hammer arm!! i checked on the websites and they said he learns it at lv35 when he evolves. but he still hasn't learned it!! please help!

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This could simply mean that you may of caught your Darmanitan after Lv 35.

A solution to your small situation could be going to the Heart Scale lady in Mistralton City, and re-learning Hammer Arm in exchange for one Heart Scale.

The building is to the right of the Pokemon center in Mistralton City, and in the house, she is the one in te top left corner. ~

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Thanks i appreciate it.