PokéBase - Pokémon Q&A
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Dusk Balls can be purchased in large amounts in the shop in Celestic Town. The shop is located in the most Northwestern corner of town. Dusk Balls are 1,500 Poke Dollars each.

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well at these locations:
pokemon leauge(they sell almost every pokeball)
orburge city
solocian town
iron island

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