PokéBase - Pokémon Q&A
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In Generation IV, the glitch was partially corrected so that a Pomeg Berry could not glitch a Pokémon with 3 or fewer HP (a Pomeg Berry will usually decrease a Pokémon's HP by 2). However, the glitch still exists but must be performed on a Pokémon with 4 or more current HP and 116 or more HP EVs. When a Pomeg Berry is consumed with more than 100 EVs, it resets the EVs to 100. With an EV total of 116, the Pokémon would lose at least 4 HP to reach 0 current HP.


So, it seems that the glitch is in fact possible in Gen 4.

Hope this helps! :)

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