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If I had a Cinderace with a Power Anklet and 255 EVs in Attack, and then I battled a Sharpedo and KOed it, would I still get the 8 Speed EVs from Power Anklet even though I didn't gain any in the attack stat?

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If a Pokémon holding a Power item gains experience from a battle, the Power item awards it additional EVs in a specific stat (in addition to the EVs it would normally earn).

I believe it would gain the Speed EVs.

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Hope I helped!

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what if the Cinderace is level 100?
I'm not entirely certain. I would think that it would gain the extra EVs, as it is in addition to the usual ones. If this answer isn't what you're looking for, I can hide it.