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I am considering giving Black Sludge to some of my Poison type Pokémon, but I want to know first if Black Sludge would still work for them even when they are Terastallized into a different type; they already keep their original STABs, but I just want to make sure for this scenario.

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The opposing Amoonguss has Terastallized into the Grass-type!
(...)
The opposing Amoonguss was hurt by its Black Sludge!

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Poison-type Pokémon that Terastallize and change their type (to anything other than Poison-) would not heal HP from Black Sludge.

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Thank you for the heads up. Now I know not to set myself up for failure in the future once I get my copy of Scarlet soon.