Meta Rate My Team PokéBase - Pokémon Q&A
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No, items that effect the exp points or EVs are still usable, so lucky egg & exp share are still usable on a pokemon with klutz. In gen V, fling doesn't work on a klutz pokemon, so holding an item with a klutz pokemon is almost useless, but trick strategies might be a nice use for this seemingly pointless ability.

Hope this helps:)

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