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EDIT: I've now beaten the E4, so please don't include TM's obtainable from shops/battle subway. Please DO tell me the list of TM's available after beating E4, like Energy Ball. (Already obtained)

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1 Badge

TM46 (Thief)
TM94 (Rock Smash)
HM01 (Cut)

2 Badges

TM41 (Torment)
TM44 (Rest)
TM45 (Attract)
TM70 (Flash)
TM86 (Grass Knot)

3 Badges

TM16 (Light Screen)
TM20 (Safeguard)
TM21 (Frustration)
TM23 (Smack Down)
TM27 (Return)
TM28 (Dig)
TM33 (Reflect)
TM34 (Sludge Wave)
TM39 (Rock Tomb)
TM48 (Round)
TM49 (Echoed Voice)
TM51 (Ally Switch)
TM59 (Incinerate)
TM60 (Quash)
TM64 (Explosion)
TM66 (Payback)
TM73 (Thunder Wave)
TM74 (Gyro Ball)
TM77 (Psych Up)
TM87 (Swagger)
TM88 (Pluck)
HM04 (Strength)

3 Badges (usually, but may vary)

TM54 (False Swipe)

4 Badges

TM22 (SolarBeam)
TM55 (Scald)

5 Badges

TM07 (Hail)
TM11 (Sunny Day)
TM18 (Rain Dance)
TM37 (Sandstorm)
TM57 (Charge Beam)
TM58 (Sky Drop)
TM61 (Will-O-Wisp)
TM65 (Shadow Claw)
TM81 (X-Scissor)
HM02 (Fly)

5 Badges (usually, but varies)

TM17 (Protect)

6 Badges

TM06 (Toxic)
TM14 (Blizzard)
TM19 (Telekinesis)
TM24 (Thunderbolt)
TM25 (Thunder)
TM31 (Brick Break)
TM38 (Fire Blast)
TM40 (Aerial Ace)
TM47 (Low Sweep)
TM52 (Focus Blast)
TM80 (Rock Slide)
TM84 (Poison Jab)
TM90 (Substitute)
TM91 (Flash Cannon)
HM03 (Surf)
HM05 (Waterfall)

7 Badges

TM05 (Roar)
TM15 (Hyper Beam)
TM30 (Shadow Ball)
TM36 (Sludge Bomb)
TM42 (Facade)
TM43 (Flame Charge)
TM56 (Fling)
TM63 (Embargo)
TM68 (Giga Impact)

8 Badges

TM02 (Dragon Claw)
TM12 (Taunt)
TM93 (Wild Charge)

8 Badges (usually, but varies)

TM10 (Hidden Power)


Source: BW TM/HM Location Guide

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