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My Brother just beat Black, and went to Black City, I asked him to get me a Fire stone (for my Vulpix), it says on Serebii and Bulbapedia that they sell Fire stones there. But when he went to the shop there were none. Does the Merchandise change from day to day? Does he need to expand Black City more before he can purchase one? Were those sites wrong?

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Basicly you need a certain amount of people
This may mean your brother will have to take people from other white forests
This tells you in more detail also where other stones are located

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