PokéBase - Pokémon Q&A
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There are numerous occasions where Sinnoh pokemon appeared in the Advanced generation, an example would be that two of the Advanced Gen movies were based on sinnoh Pokemon.("Lucario and the Mystery of Mew" & "Pokémon Ranger and the Temple of the Sea" where Manaphy was shown) Brock also had captured a Bonsly durning the Second half of the Advanced Generation. Chatot may have also appeared towards the end of the Battle Frontier season if i remember correctly... Hope this Helps :D

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lol I could tell why your answering this question:D
But were there any others?
May had a Munchlax.
oh i just remembered. Gary had an electivire at like the last episode or something
all of the ones the person above said and also may's munchlax :)
What about Weavile? I remember an episode of advanced generation with a bunch of Weaviles, but I could be wrong.
The Pokémon I remember so far are Lucario and Weavile from 'Lucario and the Mystery of Mew', Manaphy, Chatot and Mantyke from 'Manaphy and the Sea Temple', Brock's Bonsly from AG156, May's Munchlax from AG117 and then Gary's Electivire from AG192. I can't remember any others.