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For example Goh didn't make it to swsh.

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There's a ton of them. There's a lot of characters that only appear in one episode each.
well I'm asking about the ones that appear in more than episode.
Like "main" characters?
umm yeah

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This list doesn't include Ash because I am comparing him to the player character. If you disagree, please tell me.
Tracy Sketchit
Chloe
Goh
Max
Ritchie
Harrison
Drew
Harley
Morrison
Tyson
Katie
Solidad
Paul
Nando
Conway
Zoey
Kenny
Ursula
Tobias
Trip
Burgundy
Georgia
Stephan
Cameron
Virgil
Miette
Nini
Sawyer
Alaine
Horacio
Professor Ivy
Professor Cerise
Butch
Cassidy
Dr. Namba
Professor Sebastian
Brodie
Aldith
Barret
Tupp
Rapp
Zipp
Pokémon Hunter J
Viren
Delia Ketchum
Caroline
Meyer
Abe
Vivian Meridian
Lillian Meridian
Raoul Contesta
Mr. Sukizo
Casey
Angie
Khoury
Don George
Porter
Luke
Mairin
Meowth?
Wobbofuet?
Source: https://en.m.wikipedia.org/wiki/List_of_Pokémon_anime_characters
And their Bulbapedia Articles. This doesn't include Movies. Comment if I missed anything.

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Merci =)
You're welcome!