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Example: Normal Espeon vs. DW Espeon

Espeon(N) uses Toxic on Espeon(DW). I know the Magic bounce will reflect back on Espeon(N) so when Espeon(N) gets poisoned will Synchronize come into effect and make Espeon(DW) poisoned too?

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Yes, the DW Espeon will be poisoned. Magic Bounce only reflects a status once a turn.

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